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Volume 29 Issue 2
Sep.  2013
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The experimental study about the diffusivities of amino acids in aqueous solution

  • Received Date: 2004-03-15
    Accepted Date: 2004-06-07
  • Amino acid is of virtual significance to investigate t he diffusion behavior of amino acid in aqueous solution.Real-time holographic i nterferometer is employed to study the diffusion of glycine,alanine,valine aci d at 298.15K,and diffusion coefficients under 5 various concentrations are meas ured respectively.In addition,the experimental results and affecting factors a re analyzed and discussed.This investigation provides a fundament to profoundly study the diffusion and mass transfer mechanism of amino acid in aqueous soluti on.
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    SOTO-CAMPOS A M,KHOSHKBARCHI M K,VERA J H.Effect of the anion and cation of an electrolyte on the activity coefficient of DL-alanine in aqueous solutions[J].Fluid Phase Equilibria,1998,142(1~2):193~204.
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    NINNI L,MEIRELLES A J A.Water activity,ph and density of aqueous amino acids solutions[J].Biotechnology Progress,2001,17(4):703~711.
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    CHUNG Y M,VERA J H.Activity of the electrolyte and the amino acid in the systems water+dl,α-aminobutyric acid+NaCl,+NaBr,+KCl,and +KBr at 298.2K[J].Fluid Phase Equilibria,2002,203(1~2):99~110.
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    KURAMOCHI H,NORITOMI H,HOSHINO D et al.Measurements of solubilities of two amino acids in water and prediction by the UNIFAC model[J].Biotechnology Progress,1996,12(3):371~379.
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    SOTO A,ARCE A,KHOSHKBARCHI M K et al.Measurements and modeling of the solubility of a mixture of two amino acids in aqueous solutions[J].Fluid Phase Equilibria,1999,158~160:893~901.
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    LIKHODI O,CHALIKIAN T V.Partial molar volumes and adiabatic compressibilities of a series of aliphatic amino acids and oligoglycines in D2O[J].Journal of the American Chemical Society,1999,121(6):1156~1163.
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    BANIPAL T S,KAUR D,LAL P et al.Densities and viscosities of glycine,DL-α-alanine,DL-α-amino-n-butyric acid,and L-leucine in aqueous 1,2-propanediol solutions at 298.15K[J].Journal of Chemical and Engineering Data,2002,47(6):1391~1395.
    [8] 朱春英,何明霞,赵长伟 et al.L-抗坏血酸水溶液扩散系数的全息干涉法测量[J].光电子·激光,2003,14(10):1066~1069.

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    GOSTING L J.A study of the diffusion of potassium chloride in water at 25℃ with the Gouy interference method[J]. J Amer Chem Soc,1950,72(10):4418~4422.
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The experimental study about the diffusivities of amino acids in aqueous solution

  • 1. State Key Laboratory of Chemical Engineering, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China;
  • 2. College of Precision Instrument and Opto-electronics Engineering, Tianjin University, Tianjin 300072, China;
  • 3. Renqiu Jiuhuan Chemical Lmiited Corporation, Renqiu 062550, China

Abstract: Amino acid is of virtual significance to investigate t he diffusion behavior of amino acid in aqueous solution.Real-time holographic i nterferometer is employed to study the diffusion of glycine,alanine,valine aci d at 298.15K,and diffusion coefficients under 5 various concentrations are meas ured respectively.In addition,the experimental results and affecting factors a re analyzed and discussed.This investigation provides a fundament to profoundly study the diffusion and mass transfer mechanism of amino acid in aqueous soluti on.

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