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La2O3掺杂铁基记忆合金涂层组织与性能研究

Microstructure and properties of La2O3 doped Fe-based shape memory alloy coating

  • 摘要: 为了探究La2O3对激光熔覆形状记忆合金涂层组织和性能的影响, 采用宽带激光熔覆技术在42CrMo中碳钢表面制备了掺杂La2O3的Fe17Mn5Si10Cr5Ni形状记忆合金复合涂层, 通过表征得到了La2O3对复合涂层的显微组织、维氏硬度、耐磨性、耐蚀性和表面残余应力的影响结果。结果表明, La2O3显著降低了晶粒尺寸, 掺杂质量分数w=0.009时, 晶粒尺寸达到最小值3.03 μm, 而复合涂层具有最大硬度454.7 HV0.2, 磨损量最低; 并得到最低的自腐蚀电流为4.287×10-7 A/cm2, 最高的自腐蚀电位为-0.843 V, 涂层保护率达到94.83%, La2O3明显提高了涂层的耐腐蚀性能; 此时涂层的残余应力由拉应力转变为压应力, 并在Fe-Mn-Si/La2O3产生的最大残余压应力值为-378 MPa。此项研究为低应力高性能激光熔覆涂层的开发和推广提供了实践参考。

     

    Abstract: To investigate the effect of La2O3 on the organization and properties of laser melting shape memory alloy coatings, a broadband laser melting technique was used to prepare a La2O3-doped Fe17Mn5Si10Cr5Ni shape memory alloy composite coating on the surface of 42CrMo medium carbon steel. The results of the effect of La2O3 on the microstructure, Vickers hardness, wear resistance, corrosion resistance and surface residual stress of the composite coatings were obtained by characterization. The results show that La2O3 significantly reduces the grain size, when the doping mass fraction of 0.009 grain size reaches a minimum value of 3.03 μm. The composite coating has a maximum hardness of 454.7 HV0.2 and the lowest wear and the lowest self-corrosion current of 4.287×10-7 A/cm2 and the highest self-corrosion potential of -0.843 V are obtained, and the coating protection rate reaches 94.83%. La2O3 significantly improves the corrosion resistance of the coating. The residual stresses change from tensile to compressive stresses, with the highest residual compressive stress value of -378 MPa at Fe-Mn-Si/La2O3. This study provides a practical reference for the development and promotion of low-stress high-performance laser cladding coatings.

     

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