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Volume 30 Issue 2
Sep.  2013
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The nonlinear optical properties of a novel organo-metallics compound

  • A new heterocycle compound is studied with z-scan technique.The compound is a conjugate with metal atom in the center with π electronic structure.Under the CW 488nm laser excitation,the compound shows the selfdefocus property,and its third-order optical nonlinear polarization index in dichloro-methane solution is measured-1.33×10-4 esu.Besides,the optical limiting property of the compound is also investigated preliminarily based on the above experiment result.For 488nm wavelength light source,its optical limiting threshold is 25W/cm2,and the limiting mechanism should be the reverse saturable absorption effect of the excited states.All the results show that this compound have a bright future in nonlinear optical application field.
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    沈阳化工大学材料科学与工程学院 沈阳 110142

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The nonlinear optical properties of a novel organo-metallics compound

    Corresponding author: YANG Yang, yangyangzgd@yahoo.com.cn
  • 1. Department of Applied Electronics, Zhejiang Business Technology Institute, Ningbo 315012, China;
  • 2. Institute of Information, Zhejiang Industry Universiry, Hangzhou 310032, China

Abstract: A new heterocycle compound is studied with z-scan technique.The compound is a conjugate with metal atom in the center with π electronic structure.Under the CW 488nm laser excitation,the compound shows the selfdefocus property,and its third-order optical nonlinear polarization index in dichloro-methane solution is measured-1.33×10-4 esu.Besides,the optical limiting property of the compound is also investigated preliminarily based on the above experiment result.For 488nm wavelength light source,its optical limiting threshold is 25W/cm2,and the limiting mechanism should be the reverse saturable absorption effect of the excited states.All the results show that this compound have a bright future in nonlinear optical application field.

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