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Volume 38 Issue 6
Sep.  2014
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Detection of components of aromatics hydrocarbons unit based on Raman spectrometer

  • Received Date: 2013-12-18
    Accepted Date: 2014-01-28
  • In order to enhance the real-time and improve the accuracy of on-line Raman spectrometer during the testing of composition of aromatic hydrocarbon unit, the prediction model was created based on partial least square (PLS) algorithm and particle swarm optimization (PSO) algorithm. Some samples of aromatic hydrocarbons were tested. Firstly, Raman spectroscopy of aromatic composition was gotten by spectroscopy. Then, the main factors of Raman data were extracted by means of PLS algorithm in order to reduce the redundancy between data. The quick search of composition content of aromatics hydrocarbons were made by PSO algorithm to find the optimal solution. Finally, the correlation of actual values and predictive values of samples was analyzed. The results show that, compared with the old method, the new created model (Raman spectrum with PSO and PLS) has high precision and quick analysis speed. It provides a new method for detection of components of aromatic hydrocarbons unit.
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  • [1]

    LI G L,SONG G J.The application of Raman spectrometer in the process[J]. Guangdong Chemical,2008,35(5):106-109(in Chinese).
    [2]

    DING Y,CHENG M X,ZHU Q,et al. Research of prediction method of naphtha based on the on-line Raman spectrometer[J]. Sensor and Micro System,2012,30(12)69-72(in Chinese).
    [3]

    CHENG G X.The principle and application of Raman brillouin scattering[M]. Beijing: Science Press,2003:35-36(in Chinese).
    [4]

    XU L,SHAO X G.Chemometrics methods[M]. Beijing: Science Press,2004:130-163(in Chinese).
    [5]

    ROGGO Y, CHALUS P, MAURER L,et al.A review of near infrared spectroscopy and chemometrics in pharmaceutical technologies[J]. Journal of Pharmaceutical and Biomedical Analysis,2007,44(3):683-700.
    [6]

    YU Z W, CHENG M X, CAO L Y. Research of online Raman spectrometer determine naphtha PONA value [J]. Control and Instruments In Chemical Industry,2011,46(11):45-48(in Chinese).
    [7]

    LIU R.Research of adaptive particle swarm algorithm and its application in multi-objective optimization.Guangzhou:South China University of Technology,2008:9-10(in Chinese).
    [8]

    CAO L Y, CHENG M X, YU Z W, et al.Application of online Raman spectrometer in aromatic plant and fluorescence background processing[J].Control and Instruments in Chemical Industry, 2011,46(10):36-39(in Chinese).
    [9]

    YAN Y,CHENG M X,LIN J G,et al. The simulation algorithm of online Raman spectrometer measuring distillation range of petroleum products[J]. Computer Simulation, 2010, 26(9): 286-290(in Chinese).
    [10]

    COOPER J B,WISE K L,GROVES J, et al.Determination of octane number and reid vapor pressure of commercial petroleum fuels using FT-Raman spectroscopy and partial least-squares regression analysis[J].Analytical Chemistry,1995,4(10):674-964.
    [11]

    CHEN C Y,YE Y C. To solve the nonlinear equations based on particle swarm algorithm [J].Computer Applications and Software,2006,22(5):137-139(in Chinese).
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通讯作者: 陈斌, bchen63@163.com
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    沈阳化工大学材料科学与工程学院 沈阳 110142

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Detection of components of aromatics hydrocarbons unit based on Raman spectrometer

  • 1. School of Automation & Electrical Engineering, Nanjing University of Technology, Nanjing 210009, China

Abstract: In order to enhance the real-time and improve the accuracy of on-line Raman spectrometer during the testing of composition of aromatic hydrocarbon unit, the prediction model was created based on partial least square (PLS) algorithm and particle swarm optimization (PSO) algorithm. Some samples of aromatic hydrocarbons were tested. Firstly, Raman spectroscopy of aromatic composition was gotten by spectroscopy. Then, the main factors of Raman data were extracted by means of PLS algorithm in order to reduce the redundancy between data. The quick search of composition content of aromatics hydrocarbons were made by PSO algorithm to find the optimal solution. Finally, the correlation of actual values and predictive values of samples was analyzed. The results show that, compared with the old method, the new created model (Raman spectrum with PSO and PLS) has high precision and quick analysis speed. It provides a new method for detection of components of aromatic hydrocarbons unit.

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