Progress in fabrication of polymer optical fiber gratings
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摘要: 聚合物光纤光栅不仅具有体积小、质量轻、柔软、成本低等诸多优点，还因聚合物自身的特性而具有灵敏度高、响应范围宽、生物兼容性等优良特性。首先梳理了聚合物光纤的光敏性机理，概述了聚合物光纤光栅制备的刻蚀光源和方法；其次根据聚合物光纤的组成材料，概述了多种聚合物光纤光栅的制备进展和性能指标，包括聚甲基丙烯酸甲酯、环烯烃共聚物TOPAS、透明无定物氟聚合物CYTOP和聚碳酸酯。总之，目前聚甲基丙烯酸甲酯聚合物光纤光栅的研究占主导，而基于新型材料的聚合物光纤光栅因自身独特的优势也逐渐受到重视。Abstract: Polymer fiber gratings have many advantages, such as small size, light weight, softness and low cost. Due to the characteristics of polymer itself, it also has high sensitivity, wide response range and good biocompatibility. Firstly, the photosensitivity mechanism of polymer optical fiber was studied, and the etched light source and method for preparing polymer fiber gratings were summarized. Secondly, according to the composition material of polymer optical fiber, the progress in preparation and the performance of polymer fiber gratings, including polymethyl methacrylate, TOPAS, CYTOP and poly-carbonate were overviewed. At present, the study on polymethyl methacrylate polymer fiber gratings is dominant. Polymer fiber gratings based on new materials have been paid more and more attention due to their unique advantages.
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表 1 聚合物光纤光栅制备的激光器
激光器 波长 功率(密度) 光纤光栅类型 制备时间/反射率 参考文献 二倍频OPO 325nm — PMMA POFBG —/80% [5] 二倍频OPO 325nm — PMMA POFBG —/28dB [28] 钛蓝宝石激光放大器 800nm, 120fs — 多模POGBG [29] HeCd 325nm 30mW PMMA mPOFBG 6.83min/26dB [30] KrF准分子 248 nm 3mW PMMA mPOFBG 0.33min/20dB [37] HeCd 325nm 30mW PMMA mPOF LPG 7min/20dB [31] HeCd 325nm 30mW PMMA LPG 5.3min/15dB [32] HeCd 325nm 30mW PMMA TFBG —/12% [33] CO2 10μm — PMMA mPOF LPG —/25dB，13dB [40] 三倍频Nd:YAG 355nm 677mW·cm-2 单模和多模POFBG 16min/25% [41] HeCd 325nm 5W·cm-2 TOPAS mPOFBG 338min/20dB [45] HeCd 325nm 30mW TOPAS mPOFBG —/20dB [46] HeCd 325nm 6mW TOPAS POFBG 4min/30dB [47] 飞秒激光系统 517nm, 220fs — 多模CYTOP POFBG —/5.5dB [43], [44] HeCd 325nm 4mW PC mPOFBG 4min/25dB [48] 
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