Synthesis and nonlinear optical properties of C derivative by sorbate

LI Li; LIU Bing; CHEN Gai-rong; LIU Shu-zhi; TANG Guang-shi

In order to study the nonlinear optical properties of C60 derivative,a new bridged C60 derivative was prepared through the interaction between 5-(2-methylthio-4-methyl-5-pyrimidinyl)-2,4-pentadiyne-1-olsorbate and C60.The molecular structure was identified and characterized by MALDI-TOF-MS,IR,UV-vis,1H NMR,DEPT and 13C NMR spectra.The optical nonlinear properties were investigated by z-scan technique and optical limiting experiment with Q-switched,double frequency ns/ps Nd:YAG laser pulse.The experimental results show that the values of third-order optical nonlinear susceptibilities (3) and nonlinear absorption coefficient .The lower value of optical limiting clamp of C60 derivative were also found.It has a good optical limiting performance.

Corresponding author: LI Li, liliengineer@163.com;

1. Department of Chemistry and Chemical Engineering, Xinxiang University, Xinxiang 453003, China;

2. Key Laboratory of Science and Technology of Controllable Chemical Reactions of Ministry of Education, Beijing University of Chemical Technology, Beijing 100029, China

Received Date: 2011-03-04

Accepted Date: 2011-03-16

Available Online: 2012-05-25

Abstract: In order to study the nonlinear optical properties of C60 derivative,a new bridged C60 derivative was prepared through the interaction between 5-(2-methylthio-4-methyl-5-pyrimidinyl)-2,4-pentadiyne-1-olsorbate and C60.The molecular structure was identified and characterized by MALDI-TOF-MS,IR,UV-vis,1H NMR,DEPT and 13C NMR spectra.The optical nonlinear properties were investigated by z-scan technique and optical limiting experiment with Q-switched,double frequency ns/ps Nd:YAG laser pulse.The experimental results show that the values of third-order optical nonlinear susceptibilities (3) and nonlinear absorption coefficient .The lower value of optical limiting clamp of C60 derivative were also found.It has a good optical limiting performance.

HTML

Reference (16)

[1]	SCHICK G,JARROSSON T.Formation of an effective opening within the fullerene core of C60 by an unusual reaction sequence[J].General #38; Introductory Chemistry,1999,38(16):2360-2363.
[2]	ISSACS L,WEHRSIG A,DIEDERICH F.Improved purification of C60 and formation of ,- and -homoaromatic methano-bridged fullerenes by reaction with alkyl diazoacetates[J].Helvetica Chimica Acta,1993,76(3):1231-1236.
[3]	LIU S Z,TANG G S,WANG J.Synthesis,characterization and intramolecular Diels-Alder reaction tandem dehydroaromatization of a diene-diyne[J].Organic Chemistry,2005,36(49):938-939.
[4]	LI L,JIA R L,LIANG Y,et al.Synthesis of diaza-bridged C60 and its nonlinear and optical properties[J].Laser Technology,2011,35(5):636-638 (in Chinese).
[5]	SONG Y L,WANG Y X,LI J Q,et al.Excited state absorption and optical limiting properties of fullenren derivatives in red range[J].Laser Technology,1999,23 (2):77-79 (in Chinese).
[6]	TANG G S,CHEN X L,ZHANG S Y,et al.The first trisazabridged[60]fulleroid:drilling a hole on the fullerene[J].Organic Letters,2004,6(22):3925-3928.
[7]	GOH H W,GOH S H,XU G Q,et al.Optical limiting properties of double-C60-end-capped poly(ethylene oxide),double-C60-end-capped poly(ethylene oxide)/poly(ethylene oxide) blend,and double-C60-end-capped poly(ethylene oxide)/multiwalled carbon nanotube composite[J].Journal of Physical Chemistry,2003,B107 (25):6056-6062.
[8]	YANG K,KUMAR J,LEE D C,et al.Determining the dispersions of the fifth-and seventhorder nonlinear optical susceptibilities of a poly (4-BCMU) film through electroabsorption spectroscopy[J].Optics Letters,2000,25(16):1186-1188.
[9]	HE J A,YAND K,KUMAR J,et al.Electrostatic self-assembly of polydiacetylene nanocrystals:nonlinear optical properties and chain orientation[J].Journal of Physical Chemistry,1999,B103 (50):11050-11056.
[10]	ZHOU N Z,ERIKA F,ZHAO Y M.Preparation of fullerene-polyyne nanospheres via thermally induced solid-state polymerization[J].Journal of the American Chemical Society,2005,127 (41):14154-14155.
[11]	CHEN Q Y,LI K,WANG Z Y,et al.Cross-linked C60 polymer breaches the quantum gap[J].Nano Letters,2004,4 (9):1673-1675.
[12]	SUN Y P,LAWSON G E,RIGGS J E,et al.Photophysical and nonlinear optical properties of C60 fullerene derivatives[J].Journal of Physical Chemistry,1998,A102(208):5520-5528.
[13]	SONG Y L,FANG G Y,WANG Y X,et al.Excited state absorption performance and optical limiting properties of new organomctallic fullerence-C60[J].Applied Physics Letters,1999,74(3):332-334.
[14]	SHEIK B M,SAID A A,WEI T H,et al.Sensitive measurement of optical nonlinearities using a single beam[J].IEEE Journal of Quantum Electronics,1990,QE26(4):760-769.
[15]	LI L,HUANG Y Q,LIU S Z,et al.Synthesis of novel nonlinear optical naterial of 5-(2-methylthio-4-methyl-5-pyrimidinyl)-2,4-pentadiynyl sorbate[J].Journal of Luoyang Institute of Technology,2010,31 (4):101-104(in Chinese).
[16]	SHEIK B M,SAIDA A,STRYLANd E W.High-sensitivity,singlebeam a2 measurements[J].Optics Letters,1989,14 (17):955-957.

Synthesis and nonlinear optical properties of C derivative by sorbate

Abstract

References

Proportional views

通讯作者: 陈斌, bchen63@163.com

Proportional views