Study on new aggregation-induced emission material

LI Dingding; SHI Meng; LI Kaiting; MENG Xinxin; NING Guiyi; REN Zeguo

doi:10.7510/jgjs.issn.1001-3806.2016.03.021

By using fluorescence spectroscopy measurement method and ORIGIN software, new type of aggregation induced emission(AIE) material (1-rhodanine-pyrene) was studied by theoretical analysis and experimental verification and some new optical properties were discovered. The results show that when the concentration of solution dilutes, the emission peak of the sample shows a sharp blue shift. When the temperature increases, fluorescence strength of the sample enhances. These properties are different from common AIE materials, and it is related to super molecular structure induced from 1-rhodanine-pyrene aggregation in solution. The material has certain application prospect in biological imaging, medical field, sensors, photoelectric detection and organic display. The study has important significance in organic light-emitting materials.

Study on new aggregation-induced emission material

Corresponding author: SHI Meng, philipyes@163.com;

1. Shandong Provincial Key Laboratory of Laser Polarization and Information Technology, Qufu Normal University, Qufu 273165, China;

2. School of Physical Engineering, Qufu Normal University, Qufu 273165, China

Received Date: 2015-03-06

Accepted Date: 2015-04-10

Available Online: 2016-05-25

Abstract: By using fluorescence spectroscopy measurement method and ORIGIN software, new type of aggregation induced emission(AIE) material (1-rhodanine-pyrene) was studied by theoretical analysis and experimental verification and some new optical properties were discovered. The results show that when the concentration of solution dilutes, the emission peak of the sample shows a sharp blue shift. When the temperature increases, fluorescence strength of the sample enhances. These properties are different from common AIE materials, and it is related to super molecular structure induced from 1-rhodanine-pyrene aggregation in solution. The material has certain application prospect in biological imaging, medical field, sensors, photoelectric detection and organic display. The study has important significance in organic light-emitting materials.

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Reference (17)

[1]	HUO Y P, FANG X M, HUANG B H, et al. New progress of researches in fluorene compounds[J]. Chinese Journal of Organic Chemistry, 2012, 32(7):1169-1185(in Chinese).
[2]	YU S Q. The synthesis and properties of organic light-emitting material[D].Hangzhou:Zhejiang University, 2008:1-65(in Chinese).
[3]	LI Z, MILLER E W, PRALLE A, et al. A selective turn-on fluorescent sensor for imaging copper in living cells[J]. Journal of the American Chemical Society, 2006, 128(1):10-11.
[4]	LIU Y. For high efficiency organic light-emitting materials:design, synthesis and performances study[D]. Ji'nan:Shandong University, 2008:1-58(in Chinese).
[5]	CHEN J W, LAW C C W, TANG B Zh, et al. Synthesis, light emission, nanoaggregation, and restricted intramolecular rotation of 1, 1-substituted 2, 3, 4, 5-tetraphenylsiloles[J]. Chemistry of Materials, 2003, 15(7):1535-1546.
[6]	BAI W, WANG Z Y, TANG B Zh, et al. A self-assembly induced emission system constructed by the host-guest interaction of AIE-active building blocks[J]. Chemical Communications, 2015, 51(6):1089-1091.
[7]	AN B K, KWON S K, PARK S Y, et al. Enhanced emission and its switching in fluorescent organic nanoparticles[J]. Journal of the American Chemical Society, 2002, 124(48):14410-14415.
[8]	WU Q Y, PENG Q, SHUAI Z G, et al. Studies on the theory of the aggregation induced emission phenomenon[J]. Scientia Sinica (Chimica), 2013, 43(9):1078-1089.
[9]	GAO M, YU F B, CHEN L X. Fluorescent probes for hydrogen sulfide detection[J]. Progress in Chemistry, 2014, 16(6):1065-1078(in Chinese).
[10]	NING Z, CHEN Z, TIAN H. Aggregation-induced emission (AIE)-active starburst triarylamine fluorophores as potential non-doped red emitters for organic light-emitting diodes and Cl2 gas chemodosimeter[J]. Advanced Functional Materials, 2007, 17(18):3799-3807.
[11]	NAKAMURA M, SANJI T, TANAKA M. Fluorometric sensing of biogenic amines with aggregation-induced emission-active tetraphenylethenes[J]. Chemistry, 2011, A17(19):5344-5349.
[12]	LIU Y, DENG C M, TANG L, et al. Specific detection of D-glucose by atetraphenylethene-based fluorescent sensor[J]. Journal of the American Chemical Society, 2011, 133(4):660-663.
[13]	GUO Z Q, ZHU W H, TIAN H. Multiple logic fluorescent thermometer system based on N-isopropylmethacrylamide copolymer bearing dicyanomethylene-4H-pyran moiety[J]. Macromolecules, 2009, 42(5):1448-1453.
[14]	MAZUMDAR P, DAS D, SAHOO G P, et al. Aggregation induced emission enhancement of 4,4'-bis (diethylamino) benzophenone with an exceptionally large blue shift and its potential use as glucose sensor[J]. Chemical Physics, 2015, 17(5):3343-3354.
[15]	CHE Y L, CAO X L, LI Q S. Preparation and photoluminescence of nano-porous oxidized silicon[J]. Laser Technology, 2008, 32(6):605-607(in Chinese).
[16]	BI L N, CHEN G Q, WANG J, et al. Fluorescence spectra of methyl parathion and its characteristic[J]. Laser Technology, 2010, 34(2):253-257(in Chinese).
[17]	WANG W W, LI L, LI Z L, et al. Effect of temperature on the Raman spectrum of short-chain polyenes biological molecules -carotene[J]. Chemical Journal of Chinese Universities, 2010, 31(9):1864-1867(in Chinese).

Study on new aggregation-induced emission material

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