Research progress of nonlinear optical limiting materials

DU Yan-qiu; SHEN Zuo-chun

doi:10.3969/j.issn.1001-3806.2009.04.005

Volume 33 Issue 4

Aug. 2009

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Research progress of nonlinear optical limiting materials

DU Yan-qiu¹,
SHEN Zuo-chun^2, ,

1.
Department of Automatic Engineering, Heilongjiang Institute of Science and Technology, Harbin 150027, China;
2.
School of Astronautics, Harbin Institute of Technology, Harbin 150001, China

Corresponding author: SHEN Zuo-chun, szc@hit.edu.cn
Received Date: 2008-06-23
Accepted Date: 2008-09-26

Abstract

After comparing the linear,nonlinear,and phase transition property of laser protection materials,the optical limiting properties of semiconductor materials,metal phthalocyanine coordination(MPC)compounds,C60,and its derivatives, inorganic metal cluster compounds,and carbon nanotubes were comprehensively analyzed.Because of the advantages of low optical limiting threshold value,wide optical limiting bandwidth and short response time for carbon nanotube materials,its research progress in optical limiting application was further expounded.It is pointed out that carbon nanotube optical limiting material needs the further in-depth research in the aspects of materialization and devise development for better application in the optical limiting field.
- nonlinear optics,
- optical limiting,
- laser protection,
- carbon nanotubes

References

[1]	WANG Q,FAN J R.The view of anti-laser blinding thechnique of infrared-guided weapon[J].Modern Defence Technology,2001,29(6):47-50(in Chinese).
[2]	ZHA Z Zh,WANG Q.New progress of laser protection technology[J].Laser Technology,1997,21(4):246-250(in Chinese).
[3]	TIAN X S,LIU J Ch,ZHANG Y D,et al.Appealing component changes and optical properties of VO2 thin films[J].Laser Technology,2005,29(3):332-336 (in Chinese).
[4]	LUO Y Q,WANG W P,LUO F.Study on the application of vanadium pentoxide thin films in continuous laser protection[J].Applied Laser,2005,25(6):381-383 (in Chinese).
[5]	ZHANG P F,XU Y M,ZHENG F T,et al.The nonlinear optical properties of a novel organo-metallics compound[J].Laser Technology,2006,30(2):155-157(in Chinese).
[6]	MATHEWS S J,CHAITANYA K S,GIRIBABU L,et al.Large third-order optical nonlinearity and optical limiting in symmetric and unsymmetrical phthalocyanines studied using z-scan[J].Opt Commun,2007,280(1):206-212.
[7]	WANG P,ZHANG W J,HAN Y N,et al.Reverse saturable absorption and optical limiting of the C60 sol[J].Chinese Journal of Quantum Electronics,1998,15(4):390-395 (in Chinese).
[8]	QU Sh L,SONG Y L,ZHAO X L,et al.The structures and optical limiting performances of metal cluster compounds[J].Laser Technology,2001,25(3):166-169(in Chinese).
[9]	ZHANG W,JIAO W Y,SHI G,et al.The non-linear optical properties of the planar metal cluster[MoSCu4I2(py)6] doped in PMMA[J].Optical Materials,2008,31(2):218-222.
[10]	LIU L Q,ZHANG Sh,HU T J,et al.Solubilized multi-walled carbon nanotubes with broadband optical limiting effect[J].Chemical Physics Letters,2002,359(3/4):191-195.
[11]	ZANG L Y,LIU Ch L,LI Q Sh,et al.Broadband optical limiting performance of polymer-wrapped carbon nanotubes in the orange-NIR region[J].Opt Commun,2006,265(1):354-358.
[12]	XIE R H,JIANG J.Nonlinear optical properties of armchair nanotube[J].A P L,1997,71(8):1029-1031.
[13]	MARGULIS V A,SIZIKOVA T A.Theoretical study of third-order nonlinear optical response of semiconductor carbon nanotubes[J].Physica,1998,B245(2):173-189.
[14]	CHEN P,WU X,SUN X,et al.Electronic structure and optical limiting behavior of carbon nanotubes[J].Phys Rev Lett,1999,82(12):2548-2551.
[15]	WANG Q,QIN Y J,ZHU Y J,et al.Optical limiting performances of multi-walled carbon nanotubols and[C60] fullerols[J].Chemical Physics Letters,2008,457(1/3):159-162.
[16]	LUO Y Q,WANG W P,LI J F.Investigation of an optical limiting mechanism in carbon nanotube suspension[J].Laser Technology,2007,31(1):44-46(in Chinese).
[17]	ZHANG Y D,ZHANG Y J,YUANG P,et al.Optical limiting behavior of nano-gold self-assembled multi-wall carbon nanotube[J].Chinsese Optics Letters,2005,3(5):292-294.
[18]	RIGGS J E,WALKER D B,CARROLL D L,et al.Optical limiting properties of suspended and solubilized carbon nanotubes[J].J Phys Chem,2000,B104(30):7071-7076.
[19]	LI Ch,LIU Ch L,LI F Sh,et al.Optical limiting performance of two soluble multi-walled carbon nanotubes[J].Chemical Physics Letters,2003,380(1/2):201-205.
[20]	LIU L Q,ZHANG Sh,QIN Y J,et al.Solvent effects of optical limiting properties of carbon nanotubes[J].Synthetic Metals,2003,135/136:853-854.
[21]	WU H X,QIU X Q,CAO W M,et al.Polymer-wrapped multiwalled carbon nanotubes synthesized via microwave-assisted in situ emulsion polymerization and their optical limiting properties[J].Carbon,2007,45(15):2866-2872.
[22]	NIU Y Q,ZHANG P,HE Ch J,et al.Investigation of solubilized carbon nanotubes in optical limitation[J].Acta Physica Sinica,2005,54(8):3661-3664(in Chinese).
[23]	ZHANG P,NIU Y Q,HE Ch J,et al.z-scan experiment on soluble carbon nanotubes[J].Acta Physica Sinica,2006,55(6):2730-2734(in Chinese).
[24]	ZHAN H B,CHEN W Zh,WANG M Q,et al.Optical limiting effects of multi-walled carbon nanotubes suspension and silica xerogel composite[J].Chemical Physies Letters,2003,382(3/4):313-317.
[25]	ZHAN H B,ZHENG Ch,CHEN W Zh,et al.Characterization and nonlinear optical property of a multi-walled carbon nanotube/silica xerogel composite[J].Chemical Physics Letters,2005,411(4/6):373-377.

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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

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Research progress of nonlinear optical limiting materials

Corresponding author: SHEN Zuo-chun, szc@hit.edu.cn

1. Department of Automatic Engineering, Heilongjiang Institute of Science and Technology, Harbin 150027, China;

2. School of Astronautics, Harbin Institute of Technology, Harbin 150001, China

Received Date: 2008-06-23

Accepted Date: 2008-09-26

Available Online: 2009-08-25

Abstract: After comparing the linear,nonlinear,and phase transition property of laser protection materials,the optical limiting properties of semiconductor materials,metal phthalocyanine coordination(MPC)compounds,C60,and its derivatives, inorganic metal cluster compounds,and carbon nanotubes were comprehensively analyzed.Because of the advantages of low optical limiting threshold value,wide optical limiting bandwidth and short response time for carbon nanotube materials,its research progress in optical limiting application was further expounded.It is pointed out that carbon nanotube optical limiting material needs the further in-depth research in the aspects of materialization and devise development for better application in the optical limiting field.

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Reference (25)

[1]	WANG Q,FAN J R.The view of anti-laser blinding thechnique of infrared-guided weapon[J].Modern Defence Technology,2001,29(6):47-50(in Chinese).
[2]	ZHA Z Zh,WANG Q.New progress of laser protection technology[J].Laser Technology,1997,21(4):246-250(in Chinese).
[3]	TIAN X S,LIU J Ch,ZHANG Y D,et al.Appealing component changes and optical properties of VO2 thin films[J].Laser Technology,2005,29(3):332-336 (in Chinese).
[4]	LUO Y Q,WANG W P,LUO F.Study on the application of vanadium pentoxide thin films in continuous laser protection[J].Applied Laser,2005,25(6):381-383 (in Chinese).
[5]	ZHANG P F,XU Y M,ZHENG F T,et al.The nonlinear optical properties of a novel organo-metallics compound[J].Laser Technology,2006,30(2):155-157(in Chinese).
[6]	MATHEWS S J,CHAITANYA K S,GIRIBABU L,et al.Large third-order optical nonlinearity and optical limiting in symmetric and unsymmetrical phthalocyanines studied using z-scan[J].Opt Commun,2007,280(1):206-212.
[7]	WANG P,ZHANG W J,HAN Y N,et al.Reverse saturable absorption and optical limiting of the C60 sol[J].Chinese Journal of Quantum Electronics,1998,15(4):390-395 (in Chinese).
[8]	QU Sh L,SONG Y L,ZHAO X L,et al.The structures and optical limiting performances of metal cluster compounds[J].Laser Technology,2001,25(3):166-169(in Chinese).
[9]	ZHANG W,JIAO W Y,SHI G,et al.The non-linear optical properties of the planar metal cluster[MoSCu4I2(py)6] doped in PMMA[J].Optical Materials,2008,31(2):218-222.
[10]	LIU L Q,ZHANG Sh,HU T J,et al.Solubilized multi-walled carbon nanotubes with broadband optical limiting effect[J].Chemical Physics Letters,2002,359(3/4):191-195.
[11]	ZANG L Y,LIU Ch L,LI Q Sh,et al.Broadband optical limiting performance of polymer-wrapped carbon nanotubes in the orange-NIR region[J].Opt Commun,2006,265(1):354-358.
[12]	XIE R H,JIANG J.Nonlinear optical properties of armchair nanotube[J].A P L,1997,71(8):1029-1031.
[13]	MARGULIS V A,SIZIKOVA T A.Theoretical study of third-order nonlinear optical response of semiconductor carbon nanotubes[J].Physica,1998,B245(2):173-189.
[14]	CHEN P,WU X,SUN X,et al.Electronic structure and optical limiting behavior of carbon nanotubes[J].Phys Rev Lett,1999,82(12):2548-2551.
[15]	WANG Q,QIN Y J,ZHU Y J,et al.Optical limiting performances of multi-walled carbon nanotubols and[C60] fullerols[J].Chemical Physics Letters,2008,457(1/3):159-162.
[16]	LUO Y Q,WANG W P,LI J F.Investigation of an optical limiting mechanism in carbon nanotube suspension[J].Laser Technology,2007,31(1):44-46(in Chinese).
[17]	ZHANG Y D,ZHANG Y J,YUANG P,et al.Optical limiting behavior of nano-gold self-assembled multi-wall carbon nanotube[J].Chinsese Optics Letters,2005,3(5):292-294.
[18]	RIGGS J E,WALKER D B,CARROLL D L,et al.Optical limiting properties of suspended and solubilized carbon nanotubes[J].J Phys Chem,2000,B104(30):7071-7076.
[19]	LI Ch,LIU Ch L,LI F Sh,et al.Optical limiting performance of two soluble multi-walled carbon nanotubes[J].Chemical Physics Letters,2003,380(1/2):201-205.
[20]	LIU L Q,ZHANG Sh,QIN Y J,et al.Solvent effects of optical limiting properties of carbon nanotubes[J].Synthetic Metals,2003,135/136:853-854.
[21]	WU H X,QIU X Q,CAO W M,et al.Polymer-wrapped multiwalled carbon nanotubes synthesized via microwave-assisted in situ emulsion polymerization and their optical limiting properties[J].Carbon,2007,45(15):2866-2872.
[22]	NIU Y Q,ZHANG P,HE Ch J,et al.Investigation of solubilized carbon nanotubes in optical limitation[J].Acta Physica Sinica,2005,54(8):3661-3664(in Chinese).
[23]	ZHANG P,NIU Y Q,HE Ch J,et al.z-scan experiment on soluble carbon nanotubes[J].Acta Physica Sinica,2006,55(6):2730-2734(in Chinese).
[24]	ZHAN H B,CHEN W Zh,WANG M Q,et al.Optical limiting effects of multi-walled carbon nanotubes suspension and silica xerogel composite[J].Chemical Physies Letters,2003,382(3/4):313-317.
[25]	ZHAN H B,ZHENG Ch,CHEN W Zh,et al.Characterization and nonlinear optical property of a multi-walled carbon nanotube/silica xerogel composite[J].Chemical Physics Letters,2005,411(4/6):373-377.

Research progress of nonlinear optical limiting materials

Abstract

References

Proportional views

通讯作者: 陈斌, bchen63@163.com

Proportional views