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Volume 39 Issue 1
Nov.  2014
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Stability improvement of laser-induced breakdown spectroscopy based on dual-line internal standard

  • Received Date: 2014-01-13
    Accepted Date: 2014-03-24
  • Dual-line internal standard algorithm was proposed to improve the stability of laser-induced breakdown spectroscopy. The intensity of analysis line was normalized by the sum of the intensity of both the internal standard spectral lines in order to enhance the stability of the spectrum. The line Si Ⅰ 288.16nm of silicon element in steel was used for theoretical calculation and numerical simulation of dual-line internal standard algorithm, finally the universality of the algorithm was validated by taking manganese and copper lines as an example. The results show that, under the typical temperature and electron density in the laser-induced plasma, the dual-line internal standard algorithm can more effectively improve the stability of spectral lines than ordinary internal standard method.
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    CREMERS D A, CHINNI R C. Laser-induced breakdown spectroscopycapabilities and limitations[J]. Applied Spectroscopy Reviews, 2009, 44(6): 457-506.
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    GAUDIUSO R, DELL'AGLIO M, PASCALE O D, et al. Laser induced breakdown spectroscopy for elemental analysis in environmental, cultural heritage and space applications: a review of methods and results[J]. Sensors, 2010, 10(8): 7434-7468.
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    LIU X Y, WANG Z Y, HAO L Q, et al. Application of laser induced breakdown spectroscopy technology in biom edicine field[J]. Laser Technology, 2008, 32(2): 134-136 (in Chinese).
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    CRISTOFORETTI G, TOGNONI E, GIZZI L A. Thermodynamic equilibrium states in laser-induced plasmas: from the general case to laser-induced breakdown spectroscopy plasmas[J]. Spectrochimica Acta Part,2013,B90:1-22.
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    HAHN D W, OMENETTO N. Laser-induced breakdown spectroscopy (LIBS), part Ⅰ: review of basic diagnostics and plasma-particle interactions: still-challenging issues within the analytical plasma community[J]. Applied Spectroscopy, 2010, 64(12): 335A-366A.
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    LIU J, GAO X, DUAN H, et al. Latest development of laser induced breakdown spectroscopy[J]. Laser Journal, 2012,33 (1): 7-10 (in Chinese).
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    HOU Z, WANG Z, LUI S, et al. Improving data stability and prediction accuracy in laser-induced breakdown spectroscopy by utilizing a combined atomic and ionic line algorithm[J]. Journal of Analytical Atomic Spectrometry, 2013, 28(1): 107-113.
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    GRIEM H R. Plasma spectroscopy[M].New York,USA:McGraw-Hill,1964:29-31.
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    HAHN D W, OMENETTO N. Laser-induced breakdown spectroscopy (LIBS), part Ⅱ: review of instrumental and methodological approaches to material analysis and applications to different fields[J]. Applied Spectroscopy, 2012, 66(4): 347-419.
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    ZHAO X X, LUO W F, ZHANG X W, et al. Measurement of brass plasma parameters based on laser-induced breakdown spectroscopy[J]. Laser Technology, 2013, 37(1):93-96(in Chinese).
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    沈阳化工大学材料科学与工程学院 沈阳 110142

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Stability improvement of laser-induced breakdown spectroscopy based on dual-line internal standard

  • 1. College of Physics Science and Engineering Technology, Yichun University, Yichun 336000, China

Abstract: Dual-line internal standard algorithm was proposed to improve the stability of laser-induced breakdown spectroscopy. The intensity of analysis line was normalized by the sum of the intensity of both the internal standard spectral lines in order to enhance the stability of the spectrum. The line Si Ⅰ 288.16nm of silicon element in steel was used for theoretical calculation and numerical simulation of dual-line internal standard algorithm, finally the universality of the algorithm was validated by taking manganese and copper lines as an example. The results show that, under the typical temperature and electron density in the laser-induced plasma, the dual-line internal standard algorithm can more effectively improve the stability of spectral lines than ordinary internal standard method.

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