Chromium detection in water enriched with graphite based on laser-induced breakdown spectroscopy

WANG Yin; ZHAO Nan-jing; MA Ming-jun; WANG Chun-long; YU Yang; MENG De-shuo; LIU Jian-guo; LIU Wen-qing

doi:10.7510/jgjs.issn.1001-3806.2013.06.023

Volume 37 Issue 6

Sep. 2013

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Chromium detection in water enriched with graphite based on laser-induced breakdown spectroscopy

1.
Key Laboratory of Environmental Optics and Technology, Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Hefei 230031, China

Corresponding author: ZHAO Nan-jing, njzhao@aiofm.ac.cn ;
Received Date: 2013-03-08
Accepted Date: 2013-04-19

Abstract

In order to study the spectroscopy emission characteristics of chromium in water enriched with graphite based on laser induced breakdown spectroscopy, the characteristic spectral line of 425.435nm was selected for chromium in the experiment when a Nd:YAG laser in 1064nm wavelength was used as an excitation source, the echelle spectrometer and intensified charge coupled device detector with high resolution and wide spectral range were used for spectral separation and high sensitive detection. The results show that detection optimal delay time is 1100ns and gate width time is 1800ns. The calibration curve of chromium was plotted based on different concentration measurement results, and the limit of detection was 0.520mg/L. The results of the experiment provide the data reference for fast measurement of chromium in water based on laser-induced breakdown spectroscopy.
- spectroscopy,
- laser induced breakdown spectroscopy,
- water pollution,
- Cr,
- enrichment with graphite

References

[1]	ZHOU H D, PENG W Q. Water environment and water environmental remediation[M]. Beijing: Chemical Industry Press, 2005: 15-17(in Chinese).
[2]	GU Zh F, WU W. Investigation and evaluation of the heavy metal pollution situation in taihu lake[J].Gansu Science and Technology,2005,12(21):21-22(in Chinese).
[3]	CHENG X. Heavy metal pollution in taihu basin needing urgent attention[J]. Protection of Water Resources,2002,39(4):39-41(in Chinese).
[4]	KANG S X, SUN X, JU X, et al. Measurement and calculation of escape peak intensities in syn chrotron radiation X-ray fluorescence analysis[J]. Nuclear Instruments and Methods in Physics Research Section,2002,B192(4):365-369.
[5]	RAWAT M, MOTURI M C Z, SUBRAMANIAN V. Inventory compilation and distribution of heavy metals in wastewater form small-scale industrial areas of delhi, indian[J]. Journal of Environmental Monitoring(JEM),2003,5(6):906-912.
[6]	RIOS-ARANA J V, WALSH E J, GARDEA-TORRESDEY J L. Assessment of arsenic and heavy metal concentrations in water and sediments of the rio grande at EI Paso-Juarez metroplexregion[J]. Environment International, 2004, 29(7): 957-971.
[7]	PASQUINI C, CORTEZ J, SILVA L M C, et al. Laser induced breakdown spectroscopy[J].Journal of the Brazilian Chemical Society,2007, 18(3):463-512.
[8]	SONG K, LEE Y I, SNEDDON J. Recent developments in instrumentation for laser induced breakdown spectroscopy[J].Applied Spectroscopy Reviewers, 2002, 37(1):89-117.
[9]	CREMERS D A, CHINNI R C. Laser-induced breakdown spectroscopy-capabilities and limitations[J]. Applied Spectroscopy Reviews, 2009, 44(6): 457-506.
[10]	ALSULMI A Sh. Water analysis by laser induced breakdown spectroscopy(LIBS)[D].Riyadh Saudi Arabia: Kindom of Saudi Arabia Ministry of Higher Education King Saud University, 2008:5-25.
[11]	WU J Q, CHANG L, LIU L, et al.Laser-induced breakdown spectroscopy of determination of metals in solution with filter paper[J].Applied Laser, 2010, 30(4):340-343(in Chinese).
[12]	CHEN Zh J, LI H K. Fast and sensitive trace metal analysis in aqueous solutions by laser-induced breakdown spectroscopy using wood slice substrates[J]. Spectrochimica Acta Part, 2008,B63(1): 64-68.
[13]	SUN L X, YU H B, GUO Q J, et al. Development of experimental study on laser-induced breakdown spectroscopy in quantitative analysis of material[J].Chinese Journal of Scientific Instrument, 2008,29(10):2235-2240 (in Chinese).
[14]	WU J L, FU Y X. Detection of metal ions in water solution by laser induced breakdown spectroscopy[J].Spectroscopy and Spectroscopy Analysis, 2008, 28(9): 1979-1982(in Chinese).
[15]	LUI S L, GODWAL Y,TASOHUK M T,et al. Detection of lead in water using laser-induce breakdown spectroscopy and laser-induced fluotescence[J]. Analytical Chemistry, 2008, 80(6): 1995-2000.
[16]	YAN J, DING L, GE L L, et al. Research about analysis of heavy metals in liquid jet by laser-induced breakdown spectroscopy[J].Chinese Journal of Lasers, 2012, 39(2): 0215001(in Chinese).
[17]	XU L, WANG L, YAO G X, et al. Quantitative determination of Cr in liquid jets by laser-induced breakdown spectroscopy[J]. Journal of Anhui Normal University(Natural Science Edition), 2012, 35(5): 438-443(in Chinese).
[18]	XU Y, YAO M Y, LIU M H, et al. Laser induced breakdown spectroscopy of chromium in water solution[J].Acta Optica Sinica, 2011, 31(12): 093001(in Chinese).
[19]	RAI N K, RAI A K. LIBS-an efficient approch for the determination of Cr in industrial wastwater[J].Journal of Hazardous Materials, 2008, 150(3): 835-838.
[20]	WANG J Sh, QIAO D P, LU Y Zh, et al.Quantitative analysis of laser-induced breakdown spectroscopy in rocks by using intensity normalization method[J]. Chinese Journal of Lasers, 2010, 37(1): 225-230(in Chinese).
[21]	LI J, LU J D, LIN Zh X, et al. Experimental analysis of spectra of metallic elements in solid samples by laser-induced breakdown spectroscopy[J]. Chinese Journal of Lasers, 2009, 36(11): 2882-2887(in Chinese).

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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

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Chromium detection in water enriched with graphite based on laser-induced breakdown spectroscopy

Corresponding author: ZHAO Nan-jing, njzhao@aiofm.ac.cn;

1. Key Laboratory of Environmental Optics and Technology, Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Hefei 230031, China

Received Date: 2013-03-08

Accepted Date: 2013-04-19

Available Online: 2013-11-25

Abstract: In order to study the spectroscopy emission characteristics of chromium in water enriched with graphite based on laser induced breakdown spectroscopy, the characteristic spectral line of 425.435nm was selected for chromium in the experiment when a Nd:YAG laser in 1064nm wavelength was used as an excitation source, the echelle spectrometer and intensified charge coupled device detector with high resolution and wide spectral range were used for spectral separation and high sensitive detection. The results show that detection optimal delay time is 1100ns and gate width time is 1800ns. The calibration curve of chromium was plotted based on different concentration measurement results, and the limit of detection was 0.520mg/L. The results of the experiment provide the data reference for fast measurement of chromium in water based on laser-induced breakdown spectroscopy.

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Reference (21)

[1]	ZHOU H D, PENG W Q. Water environment and water environmental remediation[M]. Beijing: Chemical Industry Press, 2005: 15-17(in Chinese).
[2]	GU Zh F, WU W. Investigation and evaluation of the heavy metal pollution situation in taihu lake[J].Gansu Science and Technology,2005,12(21):21-22(in Chinese).
[3]	CHENG X. Heavy metal pollution in taihu basin needing urgent attention[J]. Protection of Water Resources,2002,39(4):39-41(in Chinese).
[4]	KANG S X, SUN X, JU X, et al. Measurement and calculation of escape peak intensities in syn chrotron radiation X-ray fluorescence analysis[J]. Nuclear Instruments and Methods in Physics Research Section,2002,B192(4):365-369.
[5]	RAWAT M, MOTURI M C Z, SUBRAMANIAN V. Inventory compilation and distribution of heavy metals in wastewater form small-scale industrial areas of delhi, indian[J]. Journal of Environmental Monitoring(JEM),2003,5(6):906-912.
[6]	RIOS-ARANA J V, WALSH E J, GARDEA-TORRESDEY J L. Assessment of arsenic and heavy metal concentrations in water and sediments of the rio grande at EI Paso-Juarez metroplexregion[J]. Environment International, 2004, 29(7): 957-971.
[7]	PASQUINI C, CORTEZ J, SILVA L M C, et al. Laser induced breakdown spectroscopy[J].Journal of the Brazilian Chemical Society,2007, 18(3):463-512.
[8]	SONG K, LEE Y I, SNEDDON J. Recent developments in instrumentation for laser induced breakdown spectroscopy[J].Applied Spectroscopy Reviewers, 2002, 37(1):89-117.
[9]	CREMERS D A, CHINNI R C. Laser-induced breakdown spectroscopy-capabilities and limitations[J]. Applied Spectroscopy Reviews, 2009, 44(6): 457-506.
[10]	ALSULMI A Sh. Water analysis by laser induced breakdown spectroscopy(LIBS)[D].Riyadh Saudi Arabia: Kindom of Saudi Arabia Ministry of Higher Education King Saud University, 2008:5-25.
[11]	WU J Q, CHANG L, LIU L, et al.Laser-induced breakdown spectroscopy of determination of metals in solution with filter paper[J].Applied Laser, 2010, 30(4):340-343(in Chinese).
[12]	CHEN Zh J, LI H K. Fast and sensitive trace metal analysis in aqueous solutions by laser-induced breakdown spectroscopy using wood slice substrates[J]. Spectrochimica Acta Part, 2008,B63(1): 64-68.
[13]	SUN L X, YU H B, GUO Q J, et al. Development of experimental study on laser-induced breakdown spectroscopy in quantitative analysis of material[J].Chinese Journal of Scientific Instrument, 2008,29(10):2235-2240 (in Chinese).
[14]	WU J L, FU Y X. Detection of metal ions in water solution by laser induced breakdown spectroscopy[J].Spectroscopy and Spectroscopy Analysis, 2008, 28(9): 1979-1982(in Chinese).
[15]	LUI S L, GODWAL Y,TASOHUK M T,et al. Detection of lead in water using laser-induce breakdown spectroscopy and laser-induced fluotescence[J]. Analytical Chemistry, 2008, 80(6): 1995-2000.
[16]	YAN J, DING L, GE L L, et al. Research about analysis of heavy metals in liquid jet by laser-induced breakdown spectroscopy[J].Chinese Journal of Lasers, 2012, 39(2): 0215001(in Chinese).
[17]	XU L, WANG L, YAO G X, et al. Quantitative determination of Cr in liquid jets by laser-induced breakdown spectroscopy[J]. Journal of Anhui Normal University(Natural Science Edition), 2012, 35(5): 438-443(in Chinese).
[18]	XU Y, YAO M Y, LIU M H, et al. Laser induced breakdown spectroscopy of chromium in water solution[J].Acta Optica Sinica, 2011, 31(12): 093001(in Chinese).
[19]	RAI N K, RAI A K. LIBS-an efficient approch for the determination of Cr in industrial wastwater[J].Journal of Hazardous Materials, 2008, 150(3): 835-838.
[20]	WANG J Sh, QIAO D P, LU Y Zh, et al.Quantitative analysis of laser-induced breakdown spectroscopy in rocks by using intensity normalization method[J]. Chinese Journal of Lasers, 2010, 37(1): 225-230(in Chinese).
[21]	LI J, LU J D, LIN Zh X, et al. Experimental analysis of spectra of metallic elements in solid samples by laser-induced breakdown spectroscopy[J]. Chinese Journal of Lasers, 2009, 36(11): 2882-2887(in Chinese).

Chromium detection in water enriched with graphite based on laser-induced breakdown spectroscopy

Abstract

References

Proportional views

通讯作者: 陈斌, bchen63@163.com

Proportional views